Abstract
Cascading chemistry! The first practical relay catalytic cascade intramolecular hydrosiloxylation of arylacetylene and asymmetric Mukaiyama aldol reaction has been established to give synthetically useful products in high yields and with excellent ee (see scheme).
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aldehydes / chemistry*
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Alkynes / chemistry*
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Catalysis
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Gold / chemistry*
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Lignans / chemistry*
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Lignans / isolation & purification
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Lignans / pharmacology
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Molecular Structure
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Organosilicon Compounds / chemical synthesis*
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Organosilicon Compounds / chemistry
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Stereoisomerism
Substances
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Aldehydes
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Alkynes
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Lignans
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Organosilicon Compounds
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Gold
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3-hydroxybutanal