Abstract
Mon ami(ne)! A general and convenient methodology for 2-aminobenzoxazinone synthesis has been developed (see scheme). Readily available 2-bromoanilines and isocyanates were used as substrates and various products have been prepared in good yields. Notably, [Mo(CO)6] as a solid CO source was applied instead of gas.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amines / chemical synthesis*
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Amines / chemistry
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Aniline Compounds / chemistry*
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Benzoxazines / chemical synthesis*
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Benzoxazines / chemistry
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Catalysis
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Combinatorial Chemistry Techniques
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Isocyanates / chemistry*
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Molecular Structure
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Palladium / chemistry*
Substances
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Amines
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Aniline Compounds
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Benzoxazines
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Isocyanates
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3-bromoaniline
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Palladium