Reducing the spin-spin interaction of stable carbon radicals

Phys Chem Chem Phys. 2013 May 7;15(17):6182-4. doi: 10.1039/c3cp50533b.

Abstract

We report the discovery that a flow of CO2, N2 or He can sufficiently reduce the spin-spin interactions of specific stable carbon centered radicals by displacing the molecular oxygen in the atmosphere enabling their detection via electron paramagnetic resonance (EPR). This finding unlike other reported effects on carbon radicals occurs under STP conditions and is reversible.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Atmosphere / chemistry
  • Carbon / chemistry*
  • Carbon Dioxide / chemistry
  • Electron Spin Resonance Spectroscopy
  • Free Radicals / chemistry
  • Helium / chemistry
  • Nitrogen / chemistry
  • Oxidation-Reduction
  • Oxygen / chemistry

Substances

  • Free Radicals
  • Carbon Dioxide
  • Helium
  • Carbon
  • Nitrogen
  • Oxygen