Homogeneous synthesis of hydroxypropyl guar gum in an ionic liquid 1-butyl-3-methylimidazolium chloride

Zhensheng Zhan; Bin Du; Shuhua Peng; Jianping He; Mingyu Deng; Jing Zhou; Ke Wang

doi:10.1016/j.carbpol.2012.12.005

Homogeneous synthesis of hydroxypropyl guar gum in an ionic liquid 1-butyl-3-methylimidazolium chloride

Carbohydr Polym. 2013 Apr 2;93(2):686-90. doi: 10.1016/j.carbpol.2012.12.005. Epub 2012 Dec 12.

Authors

Zhensheng Zhan¹, Bin Du, Shuhua Peng, Jianping He, Mingyu Deng, Jing Zhou, Ke Wang

Affiliation

¹ Polymer Research Institute, Sichuan University, Chengdu 610065, China.

PMID: 23499112
DOI: 10.1016/j.carbpol.2012.12.005

Abstract

With potassium hydroxide (KOH) as catalyst, hydroxypropyl guar gum (HPG) was successfully prepared under homogenous conditions in an ionic liquid 1-butyl-3-methylimidazolium chloride (BmimCl). The value of degree of molar substitution (MS) of HPG, which was determined by means of (1)H NMR, was easily controlled by varying the mass ratio of propylene oxide (PO) to guar gum (GG). The distribution of hydroxypropyl moieties among the seven hydroxy groups in HPGs was investigated by NMR and the results indicated that the homogeneous reaction preferentially substituted at the C3−OH of the mannosyl residues in guar gum which was quite different from the heterogeneous reaction where substitution mostly occurred at C6−OH. The average number of hydroxypropyl units per OH substitution of HPGs with MS value of 0.20, 0.37 and 0.60 was 1.82, 1.42 and 1.76, respectively.