Enantioselective palladium-catalyzed decarboxylative allylation of carbazolones: total synthesis of (-)-aspidospermidine and (+)-kopsihainanine A

Angew Chem Int Ed Engl. 2013 Apr 8;52(15):4117-21. doi: 10.1002/anie.201209878. Epub 2013 Mar 8.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbazoles / chemistry*
  • Catalysis
  • Decarboxylation
  • Heterocyclic Compounds, 4 or More Rings / chemical synthesis*
  • Heterocyclic Compounds, 4 or More Rings / chemistry
  • Indole Alkaloids / chemical synthesis*
  • Indole Alkaloids / chemistry
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Palladium / chemistry*
  • Quinolines / chemical synthesis*
  • Quinolines / chemistry
  • Stereoisomerism

Substances

  • Carbazoles
  • Heterocyclic Compounds, 4 or More Rings
  • Indole Alkaloids
  • Organometallic Compounds
  • Quinolines
  • aspidospermidine
  • kopsihainanine A
  • Palladium