Tuning the magneto-optical response of iron oxide nanocrystals in Au- and Ag-based plasmonic media

ACS Appl Mater Interfaces. 2013 Mar;5(6):1955-60. doi: 10.1021/am3027234. Epub 2013 Mar 19.

Abstract

We investigated the magneto-optical response of chemically synthesized iron oxide magnetic nanocrystals, optically coupled with ordered planar arrays of plasmonic nanoparticles. We compare the signals from two classes of systems, featuring either Au or Ag as the plasmonic counterpart. The localized surface plasmon resonance of the Ag and Au nanoparticles arrays were superimposed or detuned, respectively, with respect to the dominant magneto-optical transitions of the magnetic material. Under resonance, a significant enhancement of the magneto-optical signal was observed. In both cases, we could separate the purely plasmonic and the magnetic contributions in the magneto-optical spectrum of the optically coupled composite based on their different magnetic-field dependence.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ferric Compounds / chemistry*
  • Gold / chemistry*
  • Metal Nanoparticles / chemistry*
  • Microscopy, Atomic Force
  • Nanoparticles / chemistry*
  • Nanotechnology / methods*

Substances

  • Ferric Compounds
  • ferric oxide
  • Gold