Bio-inspired catalytic imine reduction by rhodium complexes with tethered Hantzsch pyridinium groups: evidence for direct hydride transfer from dihydropyridine to metal-activated substrate

Angew Chem Int Ed Engl. 2013 Mar 18;52(12):3411-6. doi: 10.1002/anie.201210086. Epub 2013 Feb 26.

Authors

Alex McSkimming¹, Mohan M Bhadbhade, Stephen B Colbran

Affiliation

¹ School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia.

PMID: 23441069
DOI: 10.1002/anie.201210086

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Biomimetic Materials / chemistry
Biomimetic Materials / metabolism
Catalysis
Coordination Complexes / chemistry*
Dihydropyridines / chemistry*
Electrochemical Techniques
Formates / chemistry
Hydrogenase / chemistry
Hydrogenase / metabolism
Hydrogenation
Imines / chemistry*
Molecular Conformation
Oxidation-Reduction
Rhodium / chemistry*

Substances

Coordination Complexes
Dihydropyridines
Formates
Imines
formic acid
Rhodium
Hydrogenase