5,11-Dimethyl-6,12-dimeth-oxy-indolo[3,2-b]carbazole

Acta Crystallogr Sect E Struct Rep Online. 2013 Feb 1;69(Pt 2):o255. doi: 10.1107/S1600536813001463. Epub 2013 Jan 19.

Abstract

The title compound, C(22)H(20)N(2)O(2), was prepared in a twofold Cadogan cyclization followed by double N-methyl-ation. The crystal structure is characterized by a zigzag arrangement of centrosymmetric mol-ecules. The indolocarbazole framework is essentially planar [maximum deviation = 0.028 (2) Å] and the meth-oxy groups are orthogonal to this plane [C-C-O-C torsion angle = -88.2 (2)°]. The lengths of the C-N bonds are nearly identical and all C-C bonds of the pyrrole subunit are significantly longer than the C-C bonds in the benzene rings.