6-Nitro-1,3-benzothia-zole-2(3H)-thione

Acta Crystallogr Sect E Struct Rep Online. 2013 Feb 1;69(Pt 2):o171. doi: 10.1107/S1600536812049719. Epub 2013 Jan 4.

Abstract

In the title mol-ecule, C(7)H(4)N(2)O(2)S(2), the nitro group is twisted by 5.5 (1)° from the plane of the attached benzene ring. In the crystal, N-H⋯S hydrogen bonds link pairs of mol-ecules into inversion dimers, which are linked by weak C-H⋯O inter-actions into sheets parallel to (101). The crystal packing exhibits short inter-molecular S⋯O contacts of 3.054 (4) Å and π-π inter-actions of 3.588 (5) Å between the centroids of the five- and six-membered rings of neighbouring mol-ecules.