cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N',N'-tetra-methyl-guanidine-κN'')platinum(II)

Ivan I Eliseev; Nadezhda A Bokach; Matti Haukka; Irina A Golenya

doi:10.1107/S160053681300130X

cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N',N'-tetra-methyl-guanidine-κN'')platinum(II)

Acta Crystallogr Sect E Struct Rep Online. 2013 Feb 1;69(Pt 2):m117-8. doi: 10.1107/S160053681300130X. Epub 2013 Jan 19.

Authors

Ivan I Eliseev¹, Nadezhda A Bokach, Matti Haukka, Irina A Golenya

Affiliation

¹ Department of Chemistry, St Petersburg State University, 198504 Petrodvorets, Russian Federation.

Abstract

In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an N-H⋯O hydrogen bond.