Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn(III)-substituted trilacunary Keggin tungstosilicate

Denys Shevchenko; Ping Huang; Volodymyr V Bon; Magnus F Anderlund; Vladimir N Kokozay; Stenbjörn Styring; Anders Thapper

doi:10.1039/c3dt12500a

Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn(III)-substituted trilacunary Keggin tungstosilicate

Dalton Trans. 2013 Apr 14;42(14):5130-9. doi: 10.1039/c3dt12500a.

Authors

Denys Shevchenko¹, Ping Huang, Volodymyr V Bon, Magnus F Anderlund, Vladimir N Kokozay, Stenbjörn Styring, Anders Thapper

Affiliation

¹ Analytical Chemistry, Department of Chemistry - Biomedical Center, Uppsala University, PO Box 599, S-75124, Uppsala, Sweden. denys.shevchenko@kemi.uu.se

PMID: 23403508
DOI: 10.1039/c3dt12500a

Abstract

A rare example of a "monomeric" triple transition-metal substituted Keggin anion has been synthesized and characterized by various methods including X-ray crystallography, ESI and MALDI mass spectrometry, electrochemistry, EPR, and SQUID.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Coordination Complexes / chemical synthesis
Coordination Complexes / chemistry
Crystallography, X-Ray
Electrochemical Techniques
Electron Spin Resonance Spectroscopy
Magnetics
Manganese / chemistry*
Molecular Conformation
Silicates / chemistry*
Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
Tungsten / chemistry*

Substances

Coordination Complexes
Silicates
Manganese
Tungsten