Conservation-dissipation structure of chemical reaction systems

Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Dec;86(6 Pt 2):067101. doi: 10.1103/PhysRevE.86.067101. Epub 2012 Dec 5.

Abstract

In this Brief Report, we show that balanced chemical reaction systems governed by the law of mass action have an elegant conservation-dissipation structure. From this structure a number of important conclusions can be easily deduced. In particular, with the help of this structure we can rigorously justify the classical partial equilibrium approximation in chemical kinetics.

Publication types

  • Research Support, Non-U.S. Gov't