A product of a templated solid-state photodimerization acts as a template: single-crystal reactivity in a single polymorph of a cocrystal

Suman Bhattacharya; Jelena Stojaković; Binoy K Saha; Leonard R MacGillivray

doi:10.1021/ol303283s

A product of a templated solid-state photodimerization acts as a template: single-crystal reactivity in a single polymorph of a cocrystal

Org Lett. 2013 Feb 15;15(4):744-7. doi: 10.1021/ol303283s. Epub 2013 Jan 25.

Authors

Suman Bhattacharya¹, Jelena Stojaković, Binoy K Saha, Leonard R MacGillivray

Affiliation

¹ Department of Chemistry, Pondicherry University, Puducherry 605 014, India.

PMID: 23350882
DOI: 10.1021/ol303283s

Abstract

The concept of using a product of a template-directed solid-state reaction as a template is demonstrated. A cyclobutane lined with four carboxylic acid groups is employed as the template in photoreactive cocrystals. The resulting material is shown to exhibit polymorphism.

Publication types

Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Carboxylic Acids / chemistry*
Crystallization
Cyclobutanes / chemistry*
Models, Molecular
Molecular Structure
Photochemical Processes

Substances

Carboxylic Acids
Cyclobutanes
cyclobutanol