Abstract
Pd(II)-catalyzed enantioselective C-H activation of phenylacetic acids followed by an intramolecular C-O bond formation afforded chiral benzofuranones. This reaction provides the first example of enantioselecctive C-H functionalizations through Pd(II)/Pd(IV) redox catalysis.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzofurans / chemical synthesis*
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Benzofurans / chemistry
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Catalysis
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Palladium / chemistry*
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Stereoisomerism
Substances
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Benzofurans
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Organometallic Compounds
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Palladium