Banana peel as an adsorbent for removing atrazine and ametryne from waters

J Agric Food Chem. 2013 Mar 13;61(10):2358-63. doi: 10.1021/jf304742h. Epub 2013 Jan 22.

Abstract

The feasibility of using banana peel for removal of the pesticides atrazine and ametryne from river and treated waters has been demonstrated, allowing the design of an efficient, fast, and low-cost strategy for remediation of polluted waters. The conditions for removal of these pesticides in a laboratory scale were optimized as sample volume = 50 mL, banana mass = 3.0 g, stirring time = 40 min, and no pH adjustment necessary. KF(sor) values for atrazine and ametryne were evaluated as 35.8 and 54.1 μg g(-1) (μL mL(-1)) by using liquid scintillation spectrometry. Adsorption was also evaluated by LC-ESI-MS/MS. As quantification limits were 0.10 and 0.14 μg L(-1) for both pesticides, sample preconcentration was not needed. Linear analytical curves (up to 10 μg L(-1)), precise results (RSD < 4.5%), good recoveries (82.9-106.6%), and a > 90% removal efficiency were attained for both pesticides. Water samples collected near an intensively cultivated area were adequately remedied.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Atrazine / chemistry*
  • Environmental Restoration and Remediation / instrumentation
  • Environmental Restoration and Remediation / methods*
  • Fruit / chemistry
  • Musa / chemistry*
  • Triazines / chemistry*
  • Water Pollutants, Chemical / chemistry*

Substances

  • Triazines
  • Water Pollutants, Chemical
  • ametryne
  • Atrazine