Electron doping by charge transfer at LaFeO3/Sm2CuO4 epitaxial interfaces

Adv Mater. 2013 Mar 13;25(10):1468-73. doi: 10.1002/adma.201203483. Epub 2013 Jan 4.

Abstract

Using X-ray absorption spectroscopy and electron energy loss spectroscopy with atomic-scale spatial resolution, experimental evidence for charge transfer at the interface between the Mott insulators Sm2 CuO4 and LaFeO3 is obtained. As a consequence of the charge transfer, the Sm2 CuO4 is doped with electrons and thus epitaxial Sm2 CuO4 /LaFeO3 heterostructures become metallic.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.