Repetitive synthetic method for o,o,p-oligophenylenes using C-H arylation

Kei Manabe; Takeshi Kimura

doi:10.1021/ol303327k

Repetitive synthetic method for o,o,p-oligophenylenes using C-H arylation

Org Lett. 2013 Jan 18;15(2):374-7. doi: 10.1021/ol303327k. Epub 2013 Jan 4.

Authors

Kei Manabe¹, Takeshi Kimura

Affiliation

¹ School of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Shizuoka 422-8526, Japan. manabe@u-shizuoka-ken.ac.jp

PMID: 23289430
DOI: 10.1021/ol303327k

Abstract

A synthetic method for the preparation of o,o,p-oligophenylenes has been developed. It involves Miura's C-H arylation of 2-biphenols with aryl nonaflates as the key step. Oligophenylenes with defined lengths are successfully synthesized using this method.

MeSH terms

Benzene Derivatives / chemical synthesis*
Benzene Derivatives / chemistry
Biphenyl Compounds / chemical synthesis*
Biphenyl Compounds / chemistry
Catalysis
Magnetic Resonance Spectroscopy
Molecular Structure
Palladium / chemistry*

Substances

Benzene Derivatives
Biphenyl Compounds
Palladium