A new polymorph of bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridinido-κN]zinc(II)

Acta Crystallogr C. 2013 Jan;69(Pt 1):47-51. doi: 10.1107/S0108270112050482. Epub 2012 Dec 18.

Abstract

The title compound, [Zn(C(19)H(12)N(5))(2)], crystallizes in the tetragonal space group P4(3)2(1)2, with the monomer residing on a twofold axis. The imidazole N-bound H atoms are disordered over the two positions, with refined occupancies of 0.59 (3) and 0.41 (3). The strong similarities to, and slight differences from, a reported P4(2)2(1)2 polymorph which has a 50% smaller unit-cell volume [Harvey, Baggio, Muñoz & Baggio (2003). Acta Cryst. C59, m283-m285], to which the present structure bears a group-subgroup relationship, are discussed.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallization
  • Ions / chemistry*
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Zinc / chemistry*

Substances

  • Ions
  • Organometallic Compounds
  • bis(2,6-bis(1H-benzimidazol-2-yl-kappaN3)pyridinido-kappaN)zinc(II)
  • Zinc