Conductive polyaniline helixes self-assembled in the absence of chiral dopant

Chem Commun (Camb). 2013 Feb 4;49(11):1100-2. doi: 10.1039/c2cc38575a.

Abstract

The morphological evolution of PANI helixes was achieved without the use of chiral dopants, but by a facile process through the generation of onion-like multi-lamellar vesicles used as a novel soft-template and a liquid crystal acting as a promoter for PANI polymerization and self-assembly, which is a breakthrough for the synthesis of helical structures.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ammonium Sulfate / chemistry
  • Aniline Compounds / chemistry*
  • Benzenesulfonates / chemistry
  • Circular Dichroism
  • Liquid Crystals / chemistry
  • Microscopy, Electron, Scanning
  • Microscopy, Electron, Transmission
  • Nanofibers / chemistry
  • Surface-Active Agents / chemistry

Substances

  • Aniline Compounds
  • Benzenesulfonates
  • Surface-Active Agents
  • polyaniline
  • ammonium peroxydisulfate
  • dodecylbenzenesulfonic acid
  • Ammonium Sulfate