Abstract
Two new ent-3,4-seco-labdane diterpenoids, methylcallicarpate (1) and callicarpic acid (2), were isolated from the leaves of Callicarpa nudiflora Hook et Arn. Their structures and relative configurations were established by analysis of spectroscopic data. Their absolute configurations were assigned by the application of the CD technique for the first time among the ent-3,4-seco-labdane-type diterpenes.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Callicarpa / chemistry*
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Diterpenes / chemistry
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Diterpenes / isolation & purification*
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Drugs, Chinese Herbal / chemistry
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Drugs, Chinese Herbal / isolation & purification*
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Molecular Structure
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Nuclear Magnetic Resonance, Biomolecular
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Plant Leaves / chemistry
Substances
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Diterpenes
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Drugs, Chinese Herbal
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callicarpic acid
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labdane
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methylcallicarpate