Pd-PEPPSI-IPent(Cl): an effective catalyst for the preparation of triarylamines

Ka Hou Hoi; Jennifer A Coggan; Michael G Organ

doi:10.1002/chem.201203379

Pd-PEPPSI-IPent(Cl): an effective catalyst for the preparation of triarylamines

Chemistry. 2013 Jan 14;19(3):843-5. doi: 10.1002/chem.201203379. Epub 2012 Dec 18.

Authors

Ka Hou Hoi¹, Jennifer A Coggan, Michael G Organ

Affiliation

¹ Department of Chemistry, York University, 4700 Keele Street, Toronto, ON, M3J 1P3, Canada.

PMID: 23255429
DOI: 10.1002/chem.201203379

Abstract

Third times a charm: A new Pd-NHC catalyst, Pd-PEPPSI-IPent(Cl), has been developed for applications in amination reactions for the preparation of triarylamines. The catalyst can be used under mild conditions (carbonate base/dioxane, 80 °C) to perform multiple aminations in sequence from simple aniline derivatives that contain highly base-sensitive functional groups.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Amination
Amines / chemical synthesis*
Amines / chemistry
Catalysis
Molecular Structure
Organometallic Compounds / chemistry*
Palladium / chemistry*

Substances

Amines
Organometallic Compounds
Palladium