Abstract
Enantioselective Pd(II)-catalyzed direct coupling of aminomethylferrocene derivatives with boronic acids was realized. With commercially available Boc-L-Val-OH as a ligand, planar-chiral ferrocenes could be synthesized in yields of 14-81% with up to 99% ee under mild conditions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Boronic Acids / chemistry*
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Catalysis
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Ferrous Compounds / chemical synthesis*
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Ferrous Compounds / chemistry
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Metallocenes
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Molecular Structure
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Organometallic Compounds / chemistry*
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Palladium / chemistry*
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Stereoisomerism
Substances
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Boronic Acids
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Ferrous Compounds
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Metallocenes
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Organometallic Compounds
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Palladium
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ferrocene