Enhanced phenol bioavailability by means of photocatalysis

Biodegradation. 2013 Sep;24(5):597-602. doi: 10.1007/s10532-012-9603-4. Epub 2012 Nov 15.

Abstract

Phenol was investigated for the ability of TiO2 photocatalysis to increase its bioavailability as an electron donor for denitrification. The rate of nitrate removal by denitrification was increased by up to 2.6-fold by exposing phenol to photocatalysis for 30 min, although the rate decreased with increasing photocatalysis. The increased denitrification rate appeared to be associated with the photocatalytic production of carboxylic acids, but the slow down correlated to the production of catechol and hydroquinone.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetic Acid / analysis
  • Biodegradation, Environmental / radiation effects
  • Biological Availability
  • Biological Oxygen Demand Analysis
  • Catalysis / radiation effects
  • Catechols / analysis
  • Denitrification
  • Hydroquinones / analysis
  • Light*
  • Nitrates / analysis
  • Phenol / metabolism*
  • Photochemical Processes / radiation effects*
  • Time Factors
  • Titanium / pharmacology

Substances

  • Catechols
  • Hydroquinones
  • Nitrates
  • titanium dioxide
  • Phenol
  • Titanium
  • catechol
  • Acetic Acid
  • hydroquinone