Abstract
Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Coordination Complexes / chemistry*
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Isomerism
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Manganese / chemistry*
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Nitric Oxide / chemistry*
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Spectroscopy, Fourier Transform Infrared
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Temperature
Substances
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Coordination Complexes
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Nitric Oxide
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Manganese