The lack of water is the most serious threat to humanity that leads to more efficient water and sewage treatment. Currently, many scientists are looking for new coagulants, flocculants and physicochemical methods allowing for sufficient removal of pollutants from water. The presence of various types of pigments, including chromium (III) oxide, poses the major problem. Even small amounts of these substances inhibit life processes in water. In this paper, the stability of Cr2O3 suspension in the absence and the presence of polyacrylic acid (PAA) was determined. To explain the changes in the system stability, the adsorption and electrokinetic measurements were performed. The chromium (III) oxide suspension not containing PAA is the most stable at pH=3. Under these conditions, each positively charged solid particle is surrounded by a negatively charged diffusion layer which protects from particle collision and aggregates formation (electrostatic stabilization). In turn, the Cr2O3 suspension containing the PAA is most unstable also at pH=3. In this case, the polymer causes destabilization of the colloidal suspension, which results from charge neutralization of solid particles by adsorbed PAA.