Abstract
The kinetics of the reaction of peroxyl and dpph˙ radicals with phenols H-bonded to N-bases have been studied for the first time. Electron-transfer processes are observed in MeCN but only with the dpph˙ radical.
MeSH terms
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Biphenyl Compounds / chemistry*
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Electrons*
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Free Radicals / chemistry
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Hydrogen Bonding
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Kinetics
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Molecular Structure
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Peroxides / chemistry*
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Phenols / chemistry*
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Picrates / chemistry*
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Protons*
Substances
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Biphenyl Compounds
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Free Radicals
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Peroxides
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Phenols
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Picrates
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Protons
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perhydroxyl radical
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1,1-diphenyl-2-picrylhydrazyl