5-Chloro-N-{4-oxo-2-[4-(trifluoro-meth-yl)phen-yl]-1,3-thia-zolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide

Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2969-70. doi: 10.1107/S1600536812039347. Epub 2012 Sep 22.

Abstract

In the title compound, C(25)H(17)ClF(3)N(3)O(2)S, the five-membered 1,3-thia-zolidine ring adopts a twist conformation. The three F atoms of the CF(3) group are disordered over two sets of sites with refined occupancies of 0.542 (18) and 0.458 (18). In the nine-membered 1H-indoline ring system, the 1H-pyrrole ring forms a dihedral angle of 4.7 (2)° with the benzene ring, while it is twisted at an angle of 46.5 (2)° with respect to the attached phenyl ring. The dihedral angle between the phenyl and trifluoro-methyl-substituted benzene rings is 56.0 (2)°. In the crystal, N-H⋯O hydrogen bonds connect the mol-ecules into a three-dimensional network. In addition, weak C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions are observed.