Diphenyl (methyl-amido)-phosphate

Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2934. doi: 10.1107/S160053681203869X. Epub 2012 Sep 15.

Abstract

The N-H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra-hedral coordination; its bond angles are in the range 93.96 (5)-116.83 (6)°. In the crystal, mol-ecules form centrosymmetric dimers through P=O⋯H-N hydrogen bonds.