The giant anionic polysaccharide "sacran", which is composed of 6-deoxyhexoses, pentoses, uronic acids as well as hexoses, showed hydrophobization and insolubilization phenomena in response to ultraviolet light irradiation. The sacran solution became turbid, and microparticles were formed by photoirradiation. To visualize the results of this photoreaction, anionic polysaccharide gels cross-linked by metal cations were used. As a result, we observed that sacran-gels with trivalent metal ions gradually contracted depending on the photoirradiation energy. In contrast, alginate gels used as a comparison degraded instead of contracting. This photoshrinkage of the sacran gels may be attributed to the hydrophobization of uronic acid based on photodecarboxylation. We propose that sacran-metal ion gels can function as effective, photoresponsive gels.