Abstract
Vanadium-mediated enantioselective Friedel-Crafts (FC)-type reactions were established using the dinuclear vanadium complex (R(a),S,S)-1a. The vanadium complex promoted the FC-type reaction of imines with 2-naphthols or indoles to give corresponding adducts with high enantioselectivities.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Imines / chemistry*
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Indoles / chemical synthesis*
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Indoles / chemistry*
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Molecular Structure
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Naphthols / chemistry*
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Organometallic Compounds / chemistry*
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Stereoisomerism
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Vanadium / chemistry*
Substances
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Imines
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Indoles
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Naphthols
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Organometallic Compounds
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Vanadium
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2-naphthol