Organocatalytic, oxidative, intermolecular amination and hydrazination of simple arenes at ambient temperature

Rajarshi Samanta; Jonathan O Bauer; Carsten Strohmann; Andrey P Antonchick

doi:10.1021/ol302607y

Organocatalytic, oxidative, intermolecular amination and hydrazination of simple arenes at ambient temperature

Org Lett. 2012 Nov 2;14(21):5518-21. doi: 10.1021/ol302607y. Epub 2012 Oct 16.

Authors

Rajarshi Samanta¹, Jonathan O Bauer, Carsten Strohmann, Andrey P Antonchick

Affiliation

¹ Max-Planck-Institut für Molekulare Physiologie, Abteilung Chemische Biologie, Otto-Hahn-Strasse 11, 44227 Dortmund, Germany.

PMID: 23072473
DOI: 10.1021/ol302607y

Abstract

New atom-economical, environmental friendly, direct oxidative intermolecular processes of amination and hydrazination of nonprefunctionalized arenes were developed. The products were formed in a good regioselective manner under organocatalytic conditions at ambient temperature.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Amination
Benzene Derivatives / chemical synthesis*
Benzene Derivatives / chemistry*
Catalysis
Hydrazines / chemistry*
Molecular Structure
Oxidation-Reduction
Stereoisomerism
Temperature

Substances

Benzene Derivatives
Hydrazines