Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity

Daniel P Iwaniuk; Christian Wolf

doi:10.1039/c2cc36267h

Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity

Chem Commun (Camb). 2012 Nov 25;48(91):11226-8. doi: 10.1039/c2cc36267h. Epub 2012 Oct 12.

Authors

Daniel P Iwaniuk¹, Christian Wolf

Affiliation

¹ Department of Chemistry, Georgetown University, Washington, DC 20057, USA.

PMID: 23064632
DOI: 10.1039/c2cc36267h

Abstract

A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.

Publication types

Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Acyclic Monoterpenes
Aldehydes / analysis*
Catalysis
Circular Dichroism*
Crystallography, X-Ray
Imines / chemistry
Molecular Conformation
Monoterpenes / analysis*
Palladium / chemistry
Stereoisomerism

Substances

Acyclic Monoterpenes
Aldehydes
Imines
Monoterpenes
Palladium
citronellal