Hybrid solar cells with outstanding short-circuit currents based on a room temperature soft-chemical strategy: the case of P3HT:Ag2S

J Am Chem Soc. 2012 Oct 24;134(42):17392-5. doi: 10.1021/ja307521t. Epub 2012 Oct 11.

Abstract

P3HT:Ag(2)S hybrid solar cells with broad absorption from the UV to NIR band were directly fabricated on ITO glass by using a room temperature, low energy consumption, and low-cost soft-chemical strategy. The resulting Ag(2)S nanosheet arrays facilitate the construction of a perfect percolation structure with organic P3HT to form ordered bulk heterojunctions (BHJ); without interface modification, the assembled P3HT:Ag(2)S device exhibits outstanding short-circuit current densities (J(sc)) around 20 mA cm(-2). At the current stage, the optimized device exhibited a power conversion efficiency of 2.04%.

MeSH terms

  • Electric Conductivity
  • Electric Power Supplies
  • Particle Size
  • Silver Compounds / chemistry*
  • Solar Energy*
  • Surface Properties
  • Temperature*
  • Thiophenes / chemistry*

Substances

  • Silver Compounds
  • Thiophenes
  • poly(3-hexylthiophene)
  • silver sulfide