N-(2,4-Dichloro-phen-yl)-1,3-thia-zol-2-amine

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2704. doi: 10.1107/S1600536812035301. Epub 2012 Aug 15.

Abstract

In the title mol-ecule, C(9)H(6)Cl(2)N(2)S, the mean planes of the benzene and thia-zole rings make a dihedral angle of 54.18 (8)°. In the crystal, mol-ecules are joined into dimers with an R(2) (2)(8) ring motif by pairs of N-H⋯N hydrogen bonds. These dimers are linked by C-H⋯Cl inter-actions into layers parallel to (011). The thia-zole rings form columns along the c-axis direction, with a centroid-centroid separation of 3.8581 (9) Å, indicating π-π inter-actions. An intra-molecular C-H⋯S contact also occurs.