Ortho-substituent induced triradical-containing tetranuclear oxo-vanadium(IV) cluster formation via ligand C-N bond breaking and C-O bond making

Chem Commun (Camb). 2012 Oct 21;48(82):10180-2. doi: 10.1039/c2cc35963d.

Abstract

Substituent having weak-coordination character, and attached at the ortho-carbon atom to the aniline moiety of 2-anilino-4,6-di-tert-butylphenol, provided a triradical-containing tetranuclear vanadium(IV) complex via ligand C-N bond breaking and C-O bond making.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Ligands
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry
  • Phenols / chemistry*
  • Vanadium / chemistry*

Substances

  • Ligands
  • Organometallic Compounds
  • Phenols
  • Vanadium
  • 2-anilino-4,6-di-tert-butylphenol