Abstract
A concise biomimetic total synthesis of incarvilleatone and incarviditone is achieved in one pot via the highly stereoselective hetero- and homodimerization of (±)-rengyolone, respectively. The structure of incarviditone is revised on the basis of spectroscopic and computational evidence.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzofurans / chemical synthesis*
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Benzofurans / chemistry*
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Biosynthetic Pathways
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Furans / chemistry*
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Heterocyclic Compounds, 2-Ring / chemistry*
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Heterocyclic Compounds, 4 or More Rings / chemical synthesis*
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Heterocyclic Compounds, 4 or More Rings / chemistry*
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Molecular Structure
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Nuclear Magnetic Resonance, Biomolecular
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Stereoisomerism
Substances
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Benzofurans
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Furans
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Heterocyclic Compounds, 2-Ring
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Heterocyclic Compounds, 4 or More Rings
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Rengyolone
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incarviditone
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incarvilleatone