Abstract
Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1 : 3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Actinoid Series Elements / chemistry*
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Crystallography, X-Ray
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Glycolates / chemistry*
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Ligands
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Plutonium / chemistry*
Substances
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Actinoid Series Elements
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Glycolates
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Ligands
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Organometallic Compounds
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tetra-n-octyldiglycolamide
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Plutonium
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glycolamide