catena-Poly[[(acetato-κ(2)O,O')[2-(4-oxo-1,4-dihydro-quinolin-1-yl)acetato-κO(1)]copper(II)]-μ-4,4'-bipyridine-κ(2)N:N']

Jun Wang; Chuntao Dai; Jianhua Nie

doi:10.1107/S160053681203303X

catena-Poly[[(acetato-κ(2)O,O')[2-(4-oxo-1,4-dihydro-quinolin-1-yl)acetato-κO(1)]copper(II)]-μ-4,4'-bipyridine-κ(2)N:N']

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1132. doi: 10.1107/S160053681203303X. Epub 2012 Jul 28.

Authors

Jun Wang¹, Chuntao Dai, Jianhua Nie

Affiliation

¹ Zhongshan Polytechnic, Zhongshan, Guangdong 528404, People's Republic of China.

Abstract

In the title compound, [Cu(C(11)H(8)NO(3))(CH(3)COO)(C(10)H(8)N(2))](n), the Cu(II) ion is six-coordinated by two N atoms from two 4,4'-bipyridine ligands, four O atoms from one acetate ligand, one 2-(4-oxo-1,4-dihydro-quinolin-1-yl)acetate ligand and one water mol-ecule in a distorted octa-hedral geometry. The 4,4'-bipyridine ligands inter-connect [Cu(C(11)H(8)NO(3))(CH(3)COO)] units, giving rise to a chain along [010]. These chains are further linked to each other by O-H⋯O hydrogen bonds, leading to a two-dimensional supra-molecular network parallel to (100).