(Ethano-lato-κO)[N'-(3-meth-oxy-2-oxidobenzyl-idene-κO(2))benzo-hydrazidato-κ(2)N',O]oxidovanadium(V)

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1101-2. doi: 10.1107/S1600536812032229. Epub 2012 Jul 21.

Abstract

In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethano-late anion and two O atoms and one N atom from the tridentate benzo-hydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intra-molecular O-H⋯N hydrogen bond occurs in the benzohydrazidate ligand. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal.