Hydrogen production using a molybdenum sulfide catalyst on a titanium-protected n(+)p-silicon photocathode

Angew Chem Int Ed Engl. 2012 Sep 3;51(36):9128-31. doi: 10.1002/anie.201203585. Epub 2012 Aug 9.

Abstract

A low-cost substitute: A titanium protection layer on silicon made it possible to use silicon under highly oxidizing conditions without oxidation of the silicon. Molybdenum sulfide was electrodeposited on the Ti-protected n(+)p-silicon electrode. This electrode was applied as a photocathode for water splitting and showed a greatly enhanced efficiency.