The formation of percolative composites with a high dielectric constant and high conductivity

Angew Chem Int Ed Engl. 2012 Sep 3;51(36):9123-7. doi: 10.1002/anie.201203389. Epub 2012 Aug 9.

Abstract

The dielectric constant and electrical conductivity of a composite of two insulators, poly(1,1-difluoroethylene) (yellow) and K(2)CO(3) (white), increased dramatically near the percolation threshold f(c) (f=concentration of K(2)CO(3)). This intriguing phenomenon can be interpreted in terms of interface percolation caused by the formation of chemically activated interfaces.