Photoredox catalysis for polymerization reactions

Chimia (Aarau). 2012;66(6):439-41. doi: 10.2533/chimia.2012.439.

Abstract

Photoredox catalysis is now well-known in organic synthesis for the formation of free radicals under very soft irradiations conditions (e.g. sunlight, household fluorescence or LED bulbs, Xe lamp). This method has been introduced here to the polymer chemistry area to initiate ring opening polymerizations (ROP) or free radical polymerizations (FRP). The present paper will give an up-to date situation of the photocatalyst achievements in FRP and ROP.

MeSH terms

  • Catalysis
  • Free Radicals / chemical synthesis
  • Free Radicals / chemistry
  • Oxidation-Reduction
  • Photochemical Processes
  • Polymerization
  • Polymers / chemical synthesis*
  • Polymers / chemistry
  • Time Factors

Substances

  • Free Radicals
  • Polymers