We have designed and synthesized four orange-red phosphorescent Ir(III) complexes based on the benzoylphenylpyridine ligand with fluorine and trifluoromethyl substitution. Multilayered OLEDs were fabricated using these complexes as dopant materials. Particularly, by using 1 as a dopant in the emitting layer, a highly efficient orange-red OLED was fabricated, showing a maximum luminance of 10410 cd/m2 at 10 V, a luminous efficiency of 17.47 cd/A, a power efficiency of 7.19 Im/W, an external quantum efficiency of 6.27% at 20 mA/cm2, respectively, and CIE(x,y) coordinates of (0.51, 0.48) at 10 V. Furthermore, a red OLED using dopant 2, with CIE(x,y) coordinates of (0.61, 0.39), exhibited a maximum luminance of 5797 cd/m2 at 10 V, a luminous efficiency of 11.43 cd/A at, a power efficiency of 4.12 Im/W, and an external quantum efficiency of 6.62% at 20 mA/cm2, respectively.