Colloidal CdSe/CdS dot-in-plate nanocrystals with 2D-polarized emission

ACS Nano. 2012 Aug 28;6(8):6741-50. doi: 10.1021/nn3024255. Epub 2012 Jul 23.

Abstract

We report the synthesis and properties of a novel class of nanocrystals with mixed dimensionality: a dot-in-plate core/shell nanostructure. This system was synthesized by growing a flat, disk-shaped, CdS shell on spherical CdSe cores. The anisotropic pressure induced by the shell drastically splits the first exciton fine structure in two: the "heavy hole" and "light hole" states become separated by up to 65 meV. As a result, these nanocrystals exhibit an emission strongly polarized in two dimensions, in the plane perpendicular to the wurtzite crystal c axis. We use polarization measurements on single nanocrystals and ensemble anisotropy studies to confirm the nature and position of the excitonic energy levels. These nanocrystals orient spontaneously when evaporated on a substrate, enabling a precise control of the orientation of their emission dipole.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cadmium Compounds / chemistry*
  • Colloids / chemistry
  • Light
  • Materials Testing
  • Molecular Conformation
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure*
  • Particle Size
  • Quantum Dots*
  • Refractometry / instrumentation*
  • Scattering, Radiation
  • Selenium Compounds / chemistry*
  • Sulfides / chemistry*
  • Surface Properties

Substances

  • Cadmium Compounds
  • Colloids
  • Selenium Compounds
  • Sulfides
  • cadmium sulfide
  • cadmium selenide