Cyclic process of simazine removal from waters by adsorption on zeolite H-Y and its regeneration by thermal treatment

Abstract

Removal of the agrochemical simazine from polluted waters through adsorption by zeolite Y in its protonic form was studied. The investigated parameters were: pH, time, initial simazine concentration and solid/liquid ratio. An iterative process of simazine removal from waters is proposed, featuring: (i) final agrochemical concentration well below 0.05 mg/dm(3), the maximum concentration allowed by Italian laws in wastewaters; (ii) regeneration of the adsorbent by a few minutes thermal treatment in air at about 500°C, which results in the combustion of simazine without damage of the adsorbent; (iii) destruction of the agrochemical compound by combustion.