Hetaryl-substituted phosphonium-iodonium ylides in synthesis of heterocycles

J Org Chem. 2012 Jul 6;77(13):5770-4. doi: 10.1021/jo3008836. Epub 2012 Jun 27.

Abstract

A series of hitherto unknown hetaryl-substituted (in phosphonium part) phosphonium-iodonium ylides were synthesized. The reaction of these mixed phosphonium-iodonium ylides with acetylenes opens a way to new furyl annelated phosphinolines or unusually substituted phosphininofurans.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Furans / chemical synthesis*
  • Furans / chemistry
  • Heterocyclic Compounds / chemical synthesis*
  • Heterocyclic Compounds / chemistry
  • Hydrocarbons, Iodinated / chemical synthesis*
  • Hydrocarbons, Iodinated / chemistry
  • Molecular Structure
  • Organophosphorus Compounds / chemical synthesis*
  • Organophosphorus Compounds / chemistry

Substances

  • Furans
  • Heterocyclic Compounds
  • Hydrocarbons, Iodinated
  • Organophosphorus Compounds