The composition of particulate organic fraction was determined in atmospheric aerosols emitted in two sites of central and southern Chile. In particular, polycyclic aromatic hydrocarbons (PAHs), nitrated-PAHs (N-PAHs) and polychlorinated dibenzo-p-dioxins (PCDDs) and furans (PCDFs) were investigated in both the urban site of Concepcion and the remote site of Coyhaique. The sampling was carried out with an active device during March and April 2007, and organic compounds adsorbed in air particles, having an aerodynamic diameter lower than 10 microm (PM10), were characterized using gas chromatography coupled with mass spectrometric detection (GC-MS). Aerosol contents varied from 0.004 to 3.4 ng m(-3) for PAH, from 0.007 to 3.5 pg m(-3) for N-PAH, from 0.002 to 355.7 fg Nm(-3) for PCDDs and from 0.04 to 15 fg Nm(-3) for PCDFs. As expected, the lowest values were found in the remote area. In Concepcion city, despite the low number of samples, PAH levels and diagnostic ratios of some marker compounds suggested the diesel emissions, probably coming from trucks, as the major source of particulate organic pollutants associated with direct emission. Another important source of atmospheric pollution in the urban site was likely represented by the steel industry existing in this area, outlined both by the analysis of PAH and PCDD/F levels. In the samples collected in the remote air of Coyhaique (located in the southern part of Chile), the concentration of pollutants characterized by a long lifetime, as PCDD/Fs, could be related to long-range transport phenomena, instead of local sources.