Polarization controllers based on polymer waveguide technology are demonstrated by incorporating thermo-optic birefringence modulators (BMs) and thin-film wave plates. Highly birefringent polymer materials are used to increase the efficiency of birefringence modulation in proportion to the heating power. Thin-film quarter-wave plates are fabricated by using a crosslinkable liquid crystal, reactive mesogen, and inserted between the BMs to produce static phase retardation and polarization coupling. By applying a triangular AC signal to one BM and a DC signal to another, the polarization states of the output light are modulated to cover the entire surface of the Poincaré sphere.