Designed cyanide- and phenoxide-bridged Fe(III)Mn(III) single-molecule magnet constructed by highly blocked paramagnetic precursors

Chem Commun (Camb). 2012 Jul 28;48(59):7404-6. doi: 10.1039/c2cc32503a. Epub 2012 Jun 20.

Abstract

A tetranuclear Fe(III)(2)Mn(III)(2) compound was prepared using highly blocked precursors. The well-isolated molecular entity associated with appropriate magnetic anisotropy allows for single-molecule magnet behavior.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cyanides / chemistry*
  • Ferric Compounds / chemistry*
  • Magnets / chemistry*
  • Manganese / chemistry*
  • Molecular Structure
  • Schiff Bases / chemistry

Substances

  • Cyanides
  • Ferric Compounds
  • Schiff Bases
  • Manganese