Abstract
[10]Cycloparaphenylene ([10]CPP) was selectively synthesized in four steps in 13% overall yield from commercially available 4,4'-diiodobiphenyl by using mono-I-Sn exchange, Sn-Pt transmetalation, I-Pd exchange, and subsequent oxidative coupling reactions. The single-crystal X-ray structure of [10]CPP is described.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene Derivatives / chemical synthesis*
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Benzene Derivatives / chemistry
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Crystallography, X-Ray
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Macrocyclic Compounds / chemical synthesis*
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Macrocyclic Compounds / chemistry
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Models, Molecular
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Molecular Structure
Substances
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Benzene Derivatives
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Macrocyclic Compounds